Advances in Carbohydrate Chemistry and Biochemistry, Vol. 59 by Derek Horton

By Derek Horton

Due to the fact that its inception in 1945, this serial has supplied severe and integrating articles written by way of examine experts that combine business, analytical, and technological elements of biochemistry, natural chemistry, and instrumentation technique within the learn of carbohydrates. The articles offer a definitive interpretation of the present prestige and destiny traits in carbohydrate chemistry and biochemistry. prime quality finished experiences masking all points of carbohydrate chemistry

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L-Altrose is transformed into 1,6-anhydroaltrose on treatment with aqueous acid; the acid catalyzed equilibrium is reached when the latter compound constitutes 60–65% of the total carbohydrate in solution. Apparently, the enantiomeric d-altrose has not been found in Nature. Preparation. 80 Occurrence. d-Galactose (21) is a constituent of several oligosaccharides, notably lactose, melibiose, and raffinose. Polysaccharides that yield d-galactose on hydrolysis include agar, gum arabic, mesquite gum, western larch gum, and many other plant gums and mucilages.

M. de lederkremer and c. gallo-rodriguez Preparation. 56 Occurrence. 59 Preparation. d-threo-Pentulose may be synthesized by isomerization of d-xylose in hot pyridine. 61 Occurrence. 64 naturally occurring monosaccharides 19 l-Xylulose is a constituent of the lipopolysaccharide from Yersinia enterocolitica serovar O:10,65 from which it was obtained by mild acid hydrolysis and purification by paper chromatography. Preparation. 66 Both enantiomers of xylulose were produced biologically by the oxidation of the corresponding alditol.

J. M. Gijsen, L. Qiao, W. -H. Wong, Recent advances in the chemoenzymatic synthesis of carbohydrates and carbohydrate mimetics, Chem. , 96 (1996) 443–473. 7. J. Ø. Duus, C. H. Gotfredsen, and K. Bock, Carbohydrate structural determination by NMR spectroscopy: modern methods and limitations, Chem. , 100 (2000) 4589–4614. 8. M. F. Chaplin, Gas-liquid chromatography, in M. F. Chaplin and J. F. ), Carbohydrate Analysis: A Practical Approach, IRL Press, Oxford, 1986, pp. 23–33. 9. A. Fox, S. L. Morgan, and J.

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